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n.r.davis
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Case Hardening 2nd try.
Feb 7th, 2018 at 2:16pm
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This time:  2 hours at 1640 degrees Wood Charcoal with a Barium activator.  Cool down in kiln over night.  One hour at 1430 degrees with Old Used Charcoal from Pack Annealing.  Dump in water with a bit of washing soda as a wetting agent.  Glass hard and I haven't turned it down to see how deep the case is.  David
  
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steel-pounder
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Re: Case Hardening 2nd try.
Reply #1 - Feb 9th, 2018 at 12:02am
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are you shooting for color or just hardness?
  
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n.r.davis
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Re: Case Hardening 2nd try.
Reply #2 - Feb 9th, 2018 at 8:31am
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My first concern is for hardness as to me some parts need to be hard as part of their function.  I would like to get to the point of being able to Case Harden and have them look nice also.   I will take a cut on this part to see how deep the skin goes.  Have worked on a few actions that are pretty but soft so being a old machinist  "Lipstick on a Gal that doesn't want to get her hair messed up...."  David
  
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steel-pounder
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Re: Case Hardening 2nd try.
Reply #3 - Feb 9th, 2018 at 12:08pm
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I have done some CC hardening for custom knife parts but not a lot. In the little experience that I have it is not necessary to soak above 1550. if you want a deeper case soak for a longer time. as temperature increases grain growth in the steel accelerates. large grain contribute to brittleness. 

I have had very good luck using the following for smaller parts.  pack with a mixture of wood and bone charcoal. about three part wood to one part bone has worked ell for me. soak at 1550 for as long as needed. I think I saw a chart some where as to depth of hardness in relation to time soaking.  for what I was doing one hour was enough. adding nitrogen of some form to the water helps with color also having the water oxegenated by aeration helps with color. I just put some small drip line under a piece of expanded metal in my quench tub and hooked it to a regulator on my air compressor. for the nitrogen I used ammonium nitrate fertilizer about a pound per gallon of water. 

after your soak pull the container from heat source slide off the lid and dump contents into the tub of water. dump everything in at once. 

that's pretty much all I know about it hope you find something helpful.
  
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frnkeore
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Re: Case Hardening 2nd try.
Reply #4 - Feb 9th, 2018 at 12:49pm
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Steel-Pounder,
Would you have a knife that you could show us? I'd really like to see the colors of your process.

Frank
  

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corerftech
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Re: Case Hardening 2nd try.
Reply #5 - Feb 9th, 2018 at 11:07pm
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My imperical findings (following metallurgy classes)

Longer soak, lower temp would be recommended based on my experience (I'm no expert but am heavily invested and practice often) Don't get above 1400 except to normalize or anneal. An hour at 1450-1475 and your moving LOTS of carbon as far as its going to move in low carbon alloys. Color quench in the 13's. It will still be PLENTY HARD with proper color. 

High temps work for textbook studies, makes the charts accurate (1500-1600)! Reality-- Risky- burn your alloy, have an ugly dark part with no variation, surface damage (loss of polish, distortions, cracking)- bottom line, part damage and potential if the char blows out from part, no color to show for the work!
Draw part at 400-450 F for an hour immediately.

Opposite is true I have found. Lower temps closer to mid 13's, soaked for an hour minimum/average and kept tight to the pack in quench offers better color variation and lighter colors (albinism) with saturated zones of deep color. (The mottling with electric colors everyone usually wants to see)

The intimacy that the char is bound to the part WHILE QUENCHING is what alters color performance. Poor coupling, little color, tight bound with long dwell, deep or rich acute color. This ranges from zone to zone on the material treated and the specific coupling at that zone.

Watch your kiln/oven thermoclines. The crucible can have three temps. Top/middle/bottom. All 100+F apart. Ask me how I know. 
Sucks when your kiln is short and wide. Your crucible if standing on end, top of action gets 1500, middle gets 1400, bottom gets 1350. Take temps in all ranges and ensure the TOP is the temp your after (for entire actions), I.e 1350 not 1500!

In non-metallurgical terms *my rules of thumb* for color case gun parts:
Soak Time= depth of case
QuenchTemp=color hue limitations 
Soak Temp= risk management (higher is riskier, cooler is safer)
Time part is bonded to char pack in quench= color formation potential improvement
Avoidance of char bonding at quench= color formation potential reduction
Close coupling and increased duration of char pack=increase of color or higher probability of color formation at the closely coupled zone.

Example:
A bolt that falls out of char pack at drop in quench will likely be steel grey. (airborne)
A bolt bound to char pack while immersed, likely to be deeply colored (saturated, color determined by temp at water contact) (in a mudflow of char)

  
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steel-pounder
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Re: Case Hardening 2nd try.
Reply #6 - Feb 10th, 2018 at 2:11am
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frnkeore wrote on Feb 9th, 2018 at 12:49pm:
Steel-Pounder,
Would you have a knife that you could show us? I'd really like to see the colors of your process.

Frank

Frank I am sorry but I havent done any of this for a few year and the knives i put CC hardened parts on are long sold. I mat have a picture of a dagger the guard on it being my very first try at CC hardening. if I can find it I will post in a day or two.

  
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n.r.davis
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Re: Case Hardening 2nd try.
Reply #7 - Feb 10th, 2018 at 6:47am
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Thank you for the replies.  My Kiln is 8x8x7 inches so I hope that it heats even.  Noticed when I went to temper some pin that 45 minuets was not enough time to soak them evenly.  So I will go slower, heat lower, and get out the Bubbly!  In the quench tank first!  David
  
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steel-pounder
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Re: Case Hardening 2nd try.
Reply #8 - Feb 11th, 2018 at 12:01am
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Normal carburizing temps are 1500 - 1750 f. less than 1500 and you may get some color probably not what you at looking for. no need to worry about burning your steel at these temps in a carbon pack. I have soaked steel for As long as an hour at ~2300 f in an open gas forge with out taking any precautions and not burnt my steel. it will scale heavily at this temp if the atmosphere is not slightly carburizing but that is the extent of the problem and you will not get that hot. so don't sweat it.
  
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corerftech
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Re: Case Hardening 2nd try.
Reply #9 - Feb 11th, 2018 at 12:00pm
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Not to question your methods, just covering the basics on kiln/oven use.
Preheat to useful temp.
Verify with a thermocouple secondary to the kiln PID TC, ensuring a secondary guarantee of temp
Insert the cold parts.
Monitor the temp and when the temp "stabilizes" again at the useful temp, then start the timer. Stability over a 5 min period, not an instant.
Verify the useful temp through inspection port frequently to ensure you did not preempt the useful temp stabilization. If temp has not settled, the clock should not start, your not at your working useful temp! Part was still rising to your target, not AT the target.
That may mean that your 45 minutes is extended to a significantly longer period.
No need to guess. Cheap long reach wand and meter from amazon does the trick. accurate enough (5 degrees +/-)

You might already be doing this and more to verify temp stability, target point and duration.

Your kiln is very small interior, it should not have big thermal zone differentials, if your part is horizontal you have a better chance of even heating than vertical. Mine is vertically larger and I have HOT zones on both left and right flanks. (Read: should have procured a slightly larger kiln with a larger sweet spot to fit a RB action vertically)

Mike
  
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corerftech
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Re: Case Hardening 2nd try.
Reply #10 - Feb 11th, 2018 at 12:40pm
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Again, from my personal testing (you mileage WILL vary!)

You may want to test aeration and potentially turn off aeration at time of quench. This is for you to find the happy place for you parts, your crucible stack, your pack chemistry, etc. Aerate for a LONG time, the whole time your heat cycling, preheating, etc. Then maybe turn down or off. You must test this with samples to get the outcome your after. IN ANY CASE THE HARDNESS WILL NOT BE ALTERED, it will be as hard as it could be for the soak/quench cycle used.

I found that BIG violent bubbles make AMAZING color, but spotty. Dollops of color in large flanks of tans and straws. Electric blues, like stunning blues, but only in dollops. The bubbles explode like bombs on the char pack breaking it up, creating voids. These avoids make for pockets of unprotected material that can harden in gaseous dry environments.

Smaller bubbles, the opposite. No bubbles, I noticed more uniformity in color (total coverage) or vice versa, lack of color, depending on the rate at which the char dispersed (char stack). My parts are heavy and FALL FREE from the char pack frequently. If I had the ability to have Copious CHAR avail so that the material couldn't break free, the environment will change dramatically and Ill have to alter my aeration, quench temp, etc.
I built a test case to hold a test part. I sent a Winchester SG action into the water with violent bubbles at normal temps, 100% char contact was maintained all the way to the bottom of tank. It was completely nearly one dark color (melanism)! Same temp as If I was going after mostly straw with dollops of electric blues. This for me proved the points above, contact at quench and how intimate that is maintained is what develops color, or deletes it.

Ive tried them all, I like small bubbles and violent bubbles for the crucible I have been using.

Again those bubbles agitate and cavitate the payload of parts and char and cause char to dislodge from the material at quench. That LIMITS the intimate bond and thus limits the color formation. Its a nasty viscous circle. If you skimp on char like I do due to kiln internal dimensions and crucible shape, then you may have issues with violent bubbles disrupting the bond easier than say a 3x pack (way overpacked) where the material CANT escape from the bond with char pack at water contact. The aeration saturates the water with gases but also disturbs (if bubbling at quench in any form) the char pack contact at quench.
  
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Hornetb
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Re: Case Hardening 2nd try.
Reply #11 - Feb 14th, 2018 at 12:47am
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Wrap wire and pieces of sheet steel around your part if you want to maintain you pack against the part for more colour. I describe it as shielding. 

Just means your charcoal/bone stays in contact with the metal longer. More shielding generally means more blues and colour.

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« Last Edit: Feb 14th, 2018 at 12:53am by Hornetb »  
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