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ISS
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Bhn change with age...
Sep 1st, 2021 at 1:52am
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I was always a tinkerer, probably why I never won more often.

To the point, have any of you ever bothered to load test with bullets of varying cast dates?  CBA  top shooters told me they made it a point to cast about three to four weeks before a match for max Bhn.  Three months old would soften slightly.  Six months old a bit more.  Like 1Bhn each date.  The theory was bullets of varying age/hardness would shoot to slightly different POI.

just curious,

Rich
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rgchristensen
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Re: Bhn change with age...
Reply #1 - Sep 1st, 2021 at 7:41am
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ISS wrote on Sep 1st, 2021 at 1:52am:
I was always a tinkerer, probably why I never won more often.

To the point, have any of you ever bothered to load test with bullets of varying cast dates?  CBA  top shooters told me they made it a point to cast about three to four weeks before a match for max Bhn.  Three months old would soften slightly.  Six months old a bit more.  Like 1Bhn each date.  The theory was bullets of varying age/hardness would shoot to slightly different POI.

just curious,

Rich
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RICH:
I believe this phenomenon is more common with ternary alloys, which are widely used amongst the CBA shooters.   They tend to shoot gas-check bullets at higher velocity, whilst serious BP shooters stick with the lead-tin alloys at lower velocity.

I've measured hardness variation (in both directions) with time when playing with heat-treated bullets, but never really got serious with them.  I inherited a mould for 5/16" square bullets, which is very handy for playing with heat treating bullets -- you can treat a few square bullets along with the "regular" ones and monitor the resulting hardness.

CHRIS
  
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burntwater
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Re: Bhn change with age...
Reply #2 - Sep 1st, 2021 at 9:11am
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I believe you are correct that most of us would like two cast with two part alloys but we also use lots of reclaimed with the third element antimony ( hopefully no Zn )  therefore ternary ? I’ve read of lead bullets aging and getting harder or softer can’t recall which. Verbal Smith of LBT Technology talks about this in some of his papers and I respect his opinions and advice re: lead bullets
  
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JLouis
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Re: Bhn change with age...
Reply #3 - Sep 1st, 2021 at 9:52am
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In regards to lead and tin alloys I would cast 2000+ bullets in the off season. I personally never noticed any changes as I continued to shoot them through out the new season. But I would not lube them until a few days before the next match. 
  

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Re: Bhn change with age...
Reply #4 - Sep 1st, 2021 at 10:07am
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burntwater wrote on Sep 1st, 2021 at 9:11am:
I believe you are correct that most of us would like two cast with two part alloys but we also use lots of reclaimed with the third element antimony ( hopefully no Zn )  therefore ternary ? I’ve read of lead bullets aging and getting harder or softer can’t recall which. Verbal Smith of LBT Technology talks about this in some of his papers and I respect his opinions and advice re: lead bullets


I like to avoid antimony if possible.   Scrap sheet lead and pipe don't contain much, if any.   I have observed  a sort of filmy deposit in the barrel with antimonial alloys, sort of like chalk dust on a black-board.  Easily removed with a little abrasive or brushing.   And antimony  DOES lead to unpredictable hardness variations with time and temperature.

I don't feel like a LOT of hardness is needed for black-powder target shooting applications, tho the trend in that area is toward harder bullets.  Next time out, I'm going to test some 15:1 alloy and compare to 20:1.   This is not a BIG change.  PLumber's lead is ~ 5 BHN, 20:1 ~ 8 BHN, and 15:1 ~ 9.3

With the addition of antimony and a little arsenic, I have achieved heat-treated hardness of 30+ BHN in some 25 caliber bullets, but they didn't shoot well.

CHRIS
  
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burntwater
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Re: Bhn change with age...
Reply #5 - Sep 1st, 2021 at 10:45am
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Chris good info. I know that large lead castings like sailboat ballast keels generally run 1-2% antimony. It is my understanding from discussions with a guy I knew who worked at Keelco that antimony is necessary to control shrinkage and insure a degree of rigidity at  keel bolts threads. I’ve never had any issues with small % of Sb as found in keels, cables etc.. My alloys run from 9 to 10 BHN
  
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Re: Bhn change with age...
Reply #6 - Sep 1st, 2021 at 11:06am
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What I find interesting is Linotype works extremely well in the CBA Production and the Heavy Classes. But I have never been able to make it work with any type of success in the Plainbase Class. One would tend to think that the only difference being the use of Gas Checks would not actually make that much of a difference. Especially so at the much lower velocity ranges that we typically use. I believe bullet hardness is indeed a big plus. To minimize nose slump and other unwanted variables as the bullet changes its original form while going down the barrel. 
  

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Re: Bhn change with age...
Reply #7 - Sep 1st, 2021 at 1:26pm
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I have some bullets my old friend and casting mentor left me. They were cast in 1953, and I still shoot a few from time to time. I cannot perceive any change in them in the twenty-odd years I've had them. I can't say from earlier what changes, if any. So, I suppose that to a metalurgist the change is there; to any given rifle, maybe not. 
Meant to say they are of some very hard alloy, but not full lino, according to his note in the box. I still have it as a keepsake from him.
  
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Schuetzendave
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Re: Bhn change with age...
Reply #8 - Sep 1st, 2021 at 4:37pm
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Lead:antimony alloys which have traces of arsenic (0.5% TO 1.0%) will harden over 90 days after casting whereas lead:tin alloys will soften over 90 days after casting.
I always cast my bullets in the winter and their hardness had stabilized when I shot them in the summer.

Antimony & arsenic:lead alloys can increase their hardness (quickly) by heat treating.

Handloaders' Bullet Making Annual - January 1990: "Alloys" and "Heat Treating Cast Bulllets" by Dave Scovill; Wolfe Publishing Company ISSN 0017-7393
« Last Edit: Sep 1st, 2021 at 5:11pm by Schuetzendave »  
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Re: Bhn change with age...
Reply #9 - Sep 1st, 2021 at 6:04pm
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" I always cast my bullets in the winter and their hardness has stabilized when I shot them in the summer. "

Thanks for sharing Dave and the same approach that I have also used over the years. Maybe that is why the both of us haven't seen any notable differences?
  

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Re: Bhn change with age...
Reply #10 - Sep 1st, 2021 at 6:10pm
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'...cast my bullets in the winter.... stabilized... in summer'
Well that sure would explain why the ones from the 1950s that I have seem to remain uniform. Wink
  
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Re: Bhn change with age...
Reply #11 - Sep 1st, 2021 at 6:24pm
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Could very well be! 
But who am I to say by not being educated in that field that it actually doesn't make any difference? All I have to go by is just my own personal experiences and in all honesty it probably doesn't mean anything other than to just me?
  

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