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oughtsix
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Bismuth in lead
Feb 23rd, 2018 at 4:53pm
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A local  scrap yard has an analysis gun they use to  determine the composition of a metal.  I took some lead down for analysis and it contained 0.70% Bismuth and  the guy seemed to think that may be significant.  Is it?    there are a few trace elements in the mix but it is 99% lead.    After melting into Lyman ingots, it sure has a pretty purplish color,  like oil on water

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Fred Boulton
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Re: Bismuth in lead
Reply #1 - Feb 24th, 2018 at 6:58am
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Bismuth causes your mix to expand on solidifying, thus improving the fill-out of the mold and giving well defined edges on the bullets. A very good thing to have.
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boats
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Re: Bismuth in lead
Reply #2 - Feb 24th, 2018 at 7:26am
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Interesting, Roto Metals sells Bismuth Shot. Be easy to put a little bit into your mix if it improves results.

Having said that I don’t have fill out problems and Bismuth Shot is 17 dollars per pound. 

Probably going to split a 10 lb # 2 Shot Bismuth order for Goose hunting with Vintage SXS guns with two friends. May hold some back to try in my 32/40 BS loads.  Fred any advice on % and if effects performance. Bismuth is lighter but 1 % added ought to make a .07 % weight difference. If uniform insignificant 

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Marlene
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Re: Bismuth in lead
Reply #3 - Feb 24th, 2018 at 5:21pm
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The other place we have bismuth in our lives is Cerrosafe, which could easily make its way in to a batch of lead, intentionally or not.
  
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Schuetzenmiester
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Re: Bismuth in lead
Reply #4 - Feb 24th, 2018 at 5:27pm
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What about bismuth damaging old single shot barrels?  Seems like there were issues with the nontoxic shot in older shotguns years ago.
  

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Jeff_Schultz
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Re: Bismuth in lead
Reply #5 - Feb 24th, 2018 at 5:59pm
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Schuetzenmiester wrote on Feb 24th, 2018 at 5:27pm:
What about bismuth damaging old single shot barrels?  Seems like there were issues with the nontoxic shot in older shotguns years ago.

  Bismuth shot is what to use in old shotguns when you have to use non-toxic shot. No worries. 
  

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Schuetzenmiester
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Re: Bismuth in lead
Reply #6 - Feb 24th, 2018 at 6:10pm
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Thank you.  One less thing to worry about  Wink
  

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svartkruttgris#369
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Re: Bismuth in lead
Reply #7 - Feb 24th, 2018 at 10:42pm
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Schuetzenmiester wrote on Feb 24th, 2018 at 5:27pm:
What about bismuth damaging old single shot barrels?  Seems like there were issues with the nontoxic shot in older shotguns years ago.


Used bismuth shot in my old hammer doubles, one from 1890, for up to 20 years with no problems. Kills ducks and geese as well as Cu-plated hard Pb shot, mostly because bismuth shot drags very few feathers into flesh, giving excellent penetration. It also patterns tightly and quite uniformly in my old hammer doubles.

Good stuff!!
  
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boats
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Re: Bismuth in lead
Reply #8 - Feb 25th, 2018 at 8:31am
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It’s the best non toxic, only disadvantage is the price.   

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John Boy
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Re: Bismuth in lead
Reply #9 - Feb 25th, 2018 at 12:24pm
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At 0.70% Bismuth in the alloy - that's money in the bank ...
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bnice
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Re: Bismuth in lead
Reply #10 - Feb 25th, 2018 at 1:36pm
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Does anyone know to what affect it has on hardness?
  
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svartkruttgris#369
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Re: Bismuth in lead
Reply #11 - Feb 25th, 2018 at 3:44pm
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boats wrote on Feb 25th, 2018 at 8:31am:
It’s the best non toxic, only disadvantage is the price.  

Boats


In addition to bismuth I have used Titanium Matrix ammo. It patterns more like ordinary Pb shot. Biggest drawback with it is that makers raise the chamber pressures and velocities substantialy, and hence recoil, more than I am willing to subject my old hammer doubles to for long. Kills ducks and geese nicely, especially over decoys.
  
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UtahDave
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Re: Bismuth in lead
Reply #12 - Feb 26th, 2018 at 10:08am
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I found an old paper on lead bismuth alloys.  Quite interesting if you don't mind lots of science and metallurgy.   

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Bismuth is less effective than tin in increasing alloy hardness or increasing the yield strength.  I doubt you would even be able to see any difference from bismuth in the 0.7% range.  It might be interesting to play around with some 10% to 20% bismuth in lead alloy but Bi is expensive.  I think I will stick with tin and lead.   

Dave


  
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