Here's a few notes from Sharpe's book (1937)...
For HiVel #2:
"HiVel #2 is a double-based powder with about 15% of nitroglycerine."
"It has been asserted by some authorities that HiVel is highly erosive, but it is believed that this statement is in error. Despite the fact that it has a greater potential, this powder requires a much lower weight of charge to develop equal velocities, and this, together with lower pressure, more than offsets the combustion temperature."
For Hercules #2400:
"It is a very fine-grained dense type, similar in composition to HiVel."
For HiVel #3:
"... Although first produced in 1926, it was not released to the cannister trade until early in the summer of 1935. It is slightly smaller in granulation than HiVel #2, runs reasonably well through the average powder measure and is superbly accurate and flexible. In the .300 Savage a charge as low as 10 grains can be used behind a 154-grain plain lead-based bullet developing a velocity of 1180 f.s. and a pressure too low to register. A charge of 16 grains with the same bullet gives a velocity of 1460 f.s. with a pressure of only 8400. By the same token, it operates excellently at pressures as high as 50,000 pounds or more, and in the .300 Savage with the 180-grain 30/06 bullet, 31.5 grains gives a muzzle velocity of 2420 with a pressure of 49,000 pounds. ..."
waterman,
Do you remember where you got the info on the nitroglycerin separation and detonation at sub-zero temps?
Frank,
It's long gone from dealers shelves, but it turns out that it ain't all gone.