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CajunRebel
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ADVICE - Powder Concerns
Aug 19th, 2014 at 10:08am
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Friend bought a bunch of reloading items previously belonging to a shooter he knew that died.  He sold me two cans of Dupont IMR4227 - $10.  (I've been buying IMR 4227 in plastic containers, so I know it's old.

One can had no seal, marked $17.75 R21X on top, and was filled to the bottom of the spout.  It looks similar to 4227 but I figure it was an accident waiting to happen.  I plan to dump it in a bucket of water, let it sit awhile, then throw it out.

The second can of IMR 4227 had a seal, was marked 4227 on top, and appeared filled to the typical level (3/4s).  What concerns me is 1) age, and 2) there was some dust when I pour the powder out into the powder measure.  Should I toss the second can out? Undecided

BTW - Neither cans have a strong acrid odor.
« Last Edit: Aug 19th, 2014 at 10:36am by CajunRebel »  
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JLouis
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Re: ADVICE - Free Powder Concerns
Reply #1 - Aug 19th, 2014 at 10:37am
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The first can if your are not comfortable using it is good fertilizer, I would not soak it in water simply sprinkle it accross your lawn. In regards to the second can of concern you would probably better served to simply call Hogdon Powder Co. too see what their thoughts would be. I bought an 8lb. sealed metal can of the same powder quite a few years back that was properly stored, it being the key word and it was indeed still usable. If it were me I would let the experts at Hogdon decide.

JLouis
  

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CajunRebel
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Re: ADVICE - Powder Concerns
Reply #2 - Aug 19th, 2014 at 11:18am
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Thanks.  First can dumped into yard.  Hodgdon said second can O.K., not reddish, doesn't have strong odor.
  
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JLouis
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Re: ADVICE - Powder Concerns
Reply #3 - Aug 19th, 2014 at 12:05pm
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That was good news on the second can.

JLouis
  

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CajunRebel
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Re: ADVICE - Powder Concerns
Reply #4 - Aug 19th, 2014 at 12:49pm
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Yes, it was.  But I still had misgivings.  So I dumped the entire can into a clean container and there was some red dust forming.  Not much but some.   

Not wanting to ruin my budding underwear modeling career Shocked - the second can joined the first in the yard.Cry

Bet the back yard will look great in the fall!
  
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JLouis
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Re: ADVICE - Powder Concerns
Reply #5 - Aug 19th, 2014 at 1:47pm
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Can't say that I blame you for dumping the second can, doubt creates worry and life's way to short for such things.

JLouis
  

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Hi-Wall56
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Re: ADVICE - Powder Concerns
Reply #6 - Aug 31st, 2014 at 11:22am
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I have a can of Unique that I bought back about 1987. Would the red dust also apply to it? Any suggestions would be greatly appreciated.
  
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rgchristensen
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Re: ADVICE - Powder Concerns
Reply #7 - Aug 31st, 2014 at 11:36am
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  Nitrocellulose is thermodynamically unstable.   Nitric oxide separates from it, and hastens the further decomposition.  Amine compounds are added to the powder to react with the nitric oxide and stop this.   When these are all used up, the powder is done for.   The "red dust" to look out for is not dust, but the brown nitric oxide gas.   If this is present, it will rust metal containers, degrade paper containers, and probably not have much effect on polyethylene containers.
    Absent any sharp odor or brown gas, or lots of corrosion on the inside of the can, the powder is likely OK to use, as it doesn't get stronger, but weakens on deterioration.
     I have had 2-3 cans of powder go bad in 50 years --  WWII surplus stuff.   Avoiding hot storage areas is important in long life of powder.

CHRIS 
RGChristensen

  
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ssdave
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Re: ADVICE - Powder Concerns
Reply #8 - Aug 31st, 2014 at 12:02pm
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I'm pretty conservative when it comes to safety, but you've got me beat.   

In this case, given that anything that looks like 4227 is slower powder, I would have loaded a starting load of 4227 in my browning high wall .45-70 and 300 grain bullet with each can of powder, and a known can of 4227.  Then, would have fired them across the chronograph.  If they were similar in velocity, I would have blended all the cans and made one lot and been happy to have the bargain powder.  The browning 45-70 with a 300 grain bullet can easily stand a very stiff load of essentially any IMR rifle powder, so no safety concerns in this particular instance.  This is only the situation because of the lighter bullet weight and the expansion ratio of the straight case and large bore of the .45-70.   Using this procedure with any powder and cartridge and  rifle is not a good course, just in this particular instance it would have made sense to me, at least.  I have experience with this rifle/cartidge/powder developing very hot loads in the Browning, so had some personal experience to go from also.

Unless the powder is visually degrading and has a bad smell, it is good to use.  And, it doesn't get unsafe, just gets less consistent in velocity.

dave
  
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slumlord44
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Re: ADVICE - Powder Concerns
Reply #9 - Aug 31st, 2014 at 9:16pm
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That's what I was thinking. I have shot a lot of old surplus ammo and never had a cartridge blow up. Misfire maybe. Case split yes. Not sure how it would be dangerous. May not produce as high a velocity though. Dumping it is a waste to me. Am I missing something? Anyone have bad things happen using old powder?
  
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creedmoormatch
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Re: ADVICE - Powder Concerns
Reply #10 - Sep 2nd, 2014 at 6:14am
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I believe the better choice for the disposal of old degrading nitro powder would be to apply it to my tomato plants, rather than to apply it on the lawn.

I have visions of resulting Jumbo Beefsteak tomatoes on steroids that will wake up your Buffalo Burgers beyond your wildest dreams.
  Wink

CMM
  
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creedmoormatch
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Re: ADVICE - Powder Concerns
Reply #11 - Sep 2nd, 2014 at 6:26am
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Quote:
 
Shocked - the second can joined the first in the yard.Cry

Bet the back yard will look great in the fall!


Don't be surprised if you see lots of Sci Fi type, over grown, monster Craw Dads emerging from the drainage channel after drinking the run off tainted with nitro powder!     Tongue 

It would probably be best to not pick up those nitro induced craw dads, since the nitro residue in them may cause birth defects.

I would bet that after a feast of such nitro craw dads, with lots of Tabasco hot sauce, such will make you want to get up and do what needs to be done.

CMM
« Last Edit: Sep 2nd, 2014 at 7:18am by »  
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